By Marta Galbiati
This thesis objectives molecular or natural spintronics and extra relatively the spin polarization tailoring possibilities that come up from the ferromagnetic metal/molecule hybridization at interfaces: the hot suggestion of spinterface. Molecular or natural spintronics is an rising examine box on the frontier among natural chemistry and spintronics.
The manuscript is split into 3 elements, the 1st of which introduces the fundamental ideas of spintronics and merits that molecules can convey to this box. The cutting-edge on natural and molecular spintronics is additionally offered, with a different emphasis at the physics and experimental proof for spinterfaces.
The book’s moment and 3rd elements are devoted to the 2 major experimental subject matters investigated within the thesis: Self-Assembled Monolayers (SAMs) and natural Semiconductors (OSCs). The learn of SAMs-based magnetic tunnel nanojunctions unearths the aptitude to modulate the houses of such units “at will,” due to the fact that every one a part of the molecule could be tuned independently like a “LEGO” development block. The examine of Alq3-based spin valves finds magnetoresistance results at room temperature and is geared toward figuring out the respective roles performed by way of the 2 interfaces. throughout the improvement of those structures, we exhibit their capability for spintronics and supply a great origin for spin polarization engineering on the molecular level.
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